SYNTHESIS AND EVALUATE OF SOME NEW 1,2,4-TRIAZOLES TO MODIFY EPOXY RESINS IN THE FIELD OF ANTI-MICROBIAL AND ANTI-CORROSIVE ORGANIC COATING.
- Assist. Professor, Department of Chemistry, Faculty of Science(Girls), Al-Azhar University, Cairo, Egypt.
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Some recent amino triazole derivatives mainly 4-amino-5- (trifluoromethyl)-4H-1,2,4-triazole-3-thiol (I) , 4-((4-chlorobenzylidene)amino)-5-(trifluoromethyl)-4H-1,2,4-triazole-3-thiol (?I), 4-((furan-2-ylmethylene)amino)-5-(trifluoromethyl)-4H-1,2,4-triazole-3-thiol (?I?) and Ni [ II ] complex (IV ) were synthesized and their chemical structures were confirmed by spectral data . The synthesized amino triazole compounds (I-IV) were physically incorporated into epoxy coating formula by the ratio of 0.5, 1.0, 2.0 and 3.0% by weight, in order to achieve a proper ratio of amino triazole derivatives to produce a green epoxy formulation for surface coating application. The modified epoxy varnishes were evaluated as anti-corrosion performance of mild steel coated specimens by employing salt spray test, also their antimicrobial activity against six different microbial strains mainly are Gram- positive bacteria: Staphylococcus aureus (ATCC25923) and Bacillus subtilis (ATCC6635), Gram – negative bacteria: Escherichia coli (ATCC 25922) and Salmonella typhimurium (ATCC 14028) and Yeast: Candida albicans (ATCC 10231) and Fungus: Aspergillus fumigates were screened.
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[N. Abd El-Khalik. (2017); SYNTHESIS AND EVALUATE OF SOME NEW 1,2,4-TRIAZOLES TO MODIFY EPOXY RESINS IN THE FIELD OF ANTI-MICROBIAL AND ANTI-CORROSIVE ORGANIC COATING. Int. J. of Adv. Res. 5 (Jan). 66-77] (ISSN 2320-5407). www.journalijar.com
Assist. Professor, Department of Chemistry, Faculty of Science(Girls), Al-Azhar University, Cairo, Egypt.