18Sep 2017

VOLTAMMETRIC STRUCTURE-ACTIVITY QUANTIFICATION OF REGIO-ISOMERS OF DIHYDROXYBENZOIC ACID: ELUCIDATION OF STERIC CONSTRAINTS DURING RAPID IODINATION BY AQUEOUS SOLUTIONS DEVOID OF IODIDE IONS.

  • Post-Graduate Department of Chemistry, NowrosjeeWadia College, Affiliated to the SavitribaiPhule University, Pune- 411001, India.
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The reactivity of three regio-isomers of dihydroxybenzoic acid in aqueous medium has been assessed on a quantitative scaffold by voltammetry. The rapid iodination kinetics of these isomers by aqueous molecular iodine solutions devoid of iodide ions has been investigated and the data invoked to elucidate the steric compulsions in the dynamics of these reactions.

  1. Borkar V.T., Bonde S.L and Dangat V.T., (2013) International Journal of Chemical Kinetics.,45,11,693-702.
  2. Ross A.B., Kamal-Eldin A and Aman P., (2004).,Nutr Rev.,62(3),81-95.
  3. Koskela A.,Linko-Parvinen A.M.,Hiisivuori P., Samaletdin A., Kamal-Eldin A.,Tikkanen M.J and Adlercreutz H.,(2007)., Clin Chem., 53(7), 1380.
  4. Clibbens and Nierenstein.,(1915)., J.Am.Chem.Soc.,107,1494.
  5. Mahajan S.K., Chaudhari R.Y and Wagh R.S.,(2011).,Journal of Pharmacy Research.,4(7),2285-2287.
  6. Sroka Z and Ciwoski W.,(2003).,Department of Poland.,1,50-144.
  7. Kubo I.,Xiao P and fujita K.,(2001).,Bioorganic Chemistry Letters.,11.347.
  8. Thomsen I and Torssell K.B.,(1991).,Acta.Chem.Scand.,45,539-542.
  9. , Zhengxing He.,JinghuaXue.,Xiaoping Chen andXiaoyi Wei.,(2010).,Journal of Natural Products.,73,5.
  10. Clayden J., Greeves N and Warren S.,(20120., Organic Chemistry., 2nd edition., Oxford University Press., New York.

[R. P. Yadav, B. B. Bahule, V. T. Borkar and *V. T. Dangat. (2017); VOLTAMMETRIC STRUCTURE-ACTIVITY QUANTIFICATION OF REGIO-ISOMERS OF DIHYDROXYBENZOIC ACID: ELUCIDATION OF STERIC CONSTRAINTS DURING RAPID IODINATION BY AQUEOUS SOLUTIONS DEVOID OF IODIDE IONS. Int. J. of Adv. Res. 5 (Sep). 856-860] (ISSN 2320-5407). www.journalijar.com

V.T.DANGAT
Post-Graduate Department of Chemistry, Nowrosjee Wadia College,

DOI:

Article DOI: 10.21474/IJAR01/5399      
DOI URL: http://dx.doi.org/10.21474/IJAR01/5399

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