01May 2019

SOME ORGANOTIN (IV) NITRATE ADDUCTS: SYNTHESES, FAR INFRARED AND MOSSBAUER CHARACTERIZATION.

  • Universite Cheikh Anta Diop, Faculte des Sciences et Techniques, D?partement de Chimie, Laboratoire de Chimie Minerale et Analytique (LA.CHI.MI.A.), Dakar, Senegal.
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Nine new organotin (IV) nitrate adducts of SnPh3Cl, SnMe3Cl, SnMe2Cl2 and SnBu2Cl2 have been isolated and characterized by far infrared and m?ssbauer spectroscopies. Within the proposed structures, the nitrate anion behaves as a monodentate, a bidentate, a tridentate or a monochelating ligand. All the structures are discrete and the environments at tin atoms are trigonalbipyramidal with trigonal planar SnR3 moieties in SnR3Cl adducts. Two environment types are present in SnR2Cl2 containing adducts: an octahedral and a trigonalbipyramidal. The interactions between complex-anions and cations are mainly electrostatic.


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[Serge Very Renamy, Kochikpa Yavi Ariman Okio, Mouhamadou Birame Diop and Libasse Diop. (2019); SOME ORGANOTIN (IV) NITRATE ADDUCTS: SYNTHESES, FAR INFRARED AND MOSSBAUER CHARACTERIZATION. Int. J. of Adv. Res. 7 (5). 12-22] (ISSN 2320-5407). www.journalijar.com


Mouhamadou Birame Diop
Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LA.CHI.MI.A.), Dakar, Sénégal.

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