17Jul 2017

SYNTHESIS, GROWTH AND CHARACTERIZATION OF THE METAL COORDINATED COMPLEX: 2-AMINOPYRIDINE COPPER ACETATE SINGLE CRYSTAL.

  • Asst. Prof. of Physics, PG & Research Dept. of Physics, Shanmuga Industries Arts & Science College, Tiruvannamalai-606 603, Tamilnadu, India.
  • Asst. Prof. of Physics, Dept. of Physics, Krishnasamy College of Engineering and Technology, Cuddalore, India.
  • Asst. Prof. of Physics, Dept. of Physics, University College of Engineering Panruti- 607109, Tamil Nadu, India.
Crossref Cited-by Linking logo
  • Abstract
  • Keywords
  • References
  • Cite This Article as
  • Corresponding Author

The metal coordinated complex of 2-aminopyridinium copper acetate (2APC) crystals was grown by slow evaporation solution growth method from the solvent ultrapure water. The Single crystal X-ray diffraction studies for 2APC crystal confirm the grown crystal belongs to the monoclinic crystal with the space group of P21/c in centrosymmetric system. Powder X-ray diffraction studies reveal2 the crystal perfection of as grown 2APC crystals. FTIR analysis was performed to confirm the presence of functional groups in 2APC crystal. The optical UV-Visible studies were carried out for the grown 2APC crystal. Thermal behavior of the 2APC crystal has been investigated by TG-DTA analyses. The dielectric study shows the grown crystal has low dielectric constant and dielectric loss values at high frequency region. The NMR studies shown that shifts are due to metal?ligand coordination complex. The magnetization values for 2APC crystal are the Saturation magnetization (Ms) is 0.229 x 10-3 emu/g, the retentivity (Mr) is 4.595x10-6 emu/g and coercivity (Hc) is 444.95 G. The material referred to as soft magnetic materials.

  1. Allyn, T. Londregan, Sandra Jennings, Liuqing Wei, Org. Lett. 12 (2010) 22.
  2. Cheong, S.W., Mostovoy, M. Nat. Mater. 6 (2007) 13.
  3. Deshpande, N.G , Sagade, A.A , Gudage, Y.G , Lokhande, C.D, Sharma, R, J. Alloys and Compounds 436 (2007) 421.
  4. Eerenstein, W., Mathur, N. D.,Scott, J. F. Nature 442 (2006) 759−765.
  5. Horiuchi, S., Tokura, Y. Nat. 7 (2008) 357−366
  6. Hoshino, S., Okaya, Y., Pepinsky, R. Phys. Rev. 115 (1959) 323−330.
  7. Ishibashi, Y.; Takagi, Y. Jpn. J. Appl. Phys. 15 (1976) 1621−1636.
  8. Joshi, V.N, ?Photoconductivity?, Marcel Dekker, New York (1990).
  9. Jain, P., Ramachandran, V., Clark, R. J., Zhou, H. D., Toby, B. H., Dalal, N. S., ?????Kroto, H. W., Cheetham, A. K. J. Am. Chem. Soc. 131 (2009 ) 13625 −13627. ???????????? ? Kimura, T. Ann. Rev. Mat. Res. 37 (2007) 387−413.
  10. Kagawa, F., Horiuchi, S., Tokunaga, M., Fujioka, J., Tokura, Y.Nature Phys. 6 (2010) 169−172.
  11. Mitzi, D. B. Prog. Inorg. Chem. 48 (1999) 1−121.
  12. Ohkoshi, S, Tokoro, H., Matsuda, T., Takahashi, H., Irie, H.; Hashimoto, K. ?? Chem., Int. Ed. 46 (2007) 3228−3241.
  13. Pillai, S.O, ?Solid State Physics?, New Age International Limited, New Delhi, 618 (2001).
  14. Sieron,L. Acta Cryst. E60 (2004) m577-m578.
  15. Swapan Das, K, Manas Bhunia, K, Motin Seikh, Md , Saurav Dutta, Asim Bhaumik, Dalton Trans. 40 (2011) 2932?2939.
  16. Tokura, Y., Seki, S. Adv. 22 (2010) 1554−1565.
  17. Van den Brink, J., Khomskii, D. I. J. Phys. Condens. Mat. 20 (2008) 434217.
  18. Wu, S. M, Cybart, S. A., Yu, P., Rossell, M. D., Zhang, J. X., Ramesh, R., Dynes, R. C. Nat. Mater. 9 (2010) 756−761.

[D. Gopinath, S. Rafi Ahamed and P. Srinivasan. (2017); SYNTHESIS, GROWTH AND CHARACTERIZATION OF THE METAL COORDINATED COMPLEX: 2-AMINOPYRIDINE COPPER ACETATE SINGLE CRYSTAL. Int. J. of Adv. Res. 5 (Jul). 600-608] (ISSN 2320-5407). www.journalijar.com

D.GOPINATH
ASST. PROF. OF PHYSICS, SHANMUGA INDUSTRIES ARTS & SCIENCE COLLEGE, TIRUVANNAMALAI, TAMILNADU, INDIA

DOI:

Article DOI: 10.21474/IJAR01/4758      
DOI URL: http://dx.doi.org/10.21474/IJAR01/4758

Download Full Paper

Download PDF No. of Downloads: 43 | No. of Views: 128