22Apr 2017

SPECIFIC HEAT CAPACITY OF FLOWERLIKE ZnO-PMMA COMPOSITES INVESTIGATED BY DSC.

  • Chemistry Department, Inonu University, 44280, Malatya, Turkiye.
Crossref Cited-by Linking logo
  • Abstract
  • Keywords
  • References
  • Cite This Article as
  • Corresponding Author

A series flowerlike ZnO-PMMA (FL-ZnO-PMMA) composites were synthesized from PMMA and different amount of flowerlike ZnO (FL-ZnO) particles via the solution direct-dispersing and in-situ polymerization method. FL-ZnO particles have been synthesized using the hydrothermally technique. Effects of synthesis conditions on the crystal structure, crystallite size, microstructure and morphological properties of the produced FL-ZnO particles were investigated by FTIR, X-ray and SEM. The prepared ZnO nanostructures with flowerlike morphology have been blended with methyl methacrylate and this solution was polymerized by in-situ radical polymerization technique to prepare FL-ZnO-PMMA composite films. The obtained nanocomposite films are highly transparent, flexible and chemically stable. Investigation of specific heat capacity of composites is achieved by using differential scanning calorimeter. This study is unique about exploration of effect of FL-ZnO amount on specific heat capacity of polymeric composites.

  1. Schmidt G; Malwitz MM. Properties of polymer?nanoparticle composites, Current Opinion in Colloid and Interface Science, 2003, 8, 103?108.
  2. Zhaoa X; Lva L; Pana B; Zhanga W; Zhanga S; Zhanga Q. Polymer-supported nanocomposites for environmental application: A review., Chemical Engineering Journal, 2011, 170, 381?394.
  3. Tjong SC. Structural and mechanical properties of polymer nanocomposites, Materials Science and Engineering, 2006, 53, 73?197.
  4. Vaia RA; Maguire JF. Polymer nanocomposites with prescribed porphology: going beyond nanoparticle-filled polymers. Chem. Mater. 2007, 19, 2736-2751
  5. Hussain F; Hojjatı M; Okamoto M; Gorga RE. Review article: polymer-matrix nanocomposites, processing, manufacturing, and application: an overview. Journal of Composite Materials. 2006, 40, 1511?1516.
  6. Paul DR; Robeson LM. Polymer nanotechnology: nanocomposites. Polymer. 2008, 49, 3187?3204.
  7. Crosby AJ; Lee Jyo. Polymer nanocomposites: The ?nano? effect on mechanical properties. Polymer Reviews. 2007, 47, 217?229.
  8. Jordana J; Jacobb KI; Tannenbaumc R; Sharafb MA; Jasiukd I. Experimental trends in nanocomposites?a review. polymer Materials Science and Engineering. 2005, 393, 1?11.
  9. Mor?ntale E; Harabor A; Constantinescu C; Rotaru P. Use of heat flows from DSC curve for calculation of specific heat of the solid materials. Physics AUC. 2013, 23, 89-94.
  10. Xu SX; Li Y; Feng YP. Study of temperature prole and specific heat capacity in temperature modulated DSC with a low sample heat diffusivity. Thermochimica Acta. 2000, 360, 131-140.
  11. Flynn JH; Levin DM. A method for the determination of thermal conductivity of sheet materials by DSC. Thermochimica Acta. 1988, 126, 93-100.
  12. K?k M; Demirelli K; Aydogdu Y. Thermophysical properties of blend of poly(vinyl chloride) with poly (ısobornyl acrylate). International Journal of Science & Technology. 2008, 3, 37-42.
  13. Weidenfeller B; H?fer M; Schilling FR. Thermal conductivity, thermal diffusivity, and specific heat capacity of particle filled polypropylene. Composites Part A: Applied Science and Manufacturing. 2004; 35(4), 423-429.
  14. Cezairliyan A; Miiller AP. Specific heat capacity and electrical resistivity of a carbon-carbon composite in the range 1500?3000 K by a pulse heating method. International Journal of Thermophysics. 1980, 1(3), 317-326.
  15. Hu Y; Zhou S; Wu L. Surface mechanical properties of transparent poly(methyl methacrylate)/ zirconia nanocomposites prepared by in situ bulk polymerization. Polymer. 2009, 50, 3609?3616.
  16. Laachachi A; Ruch D; Addiego F; Ferriol M; Cochez M; Cuesta JML. Effect of ZnO and organo-modified montmorillonite on thermal degradation of poly(methyl methacrylate) nanocomposites. Polymer Degradation and Stability. 2009, 94, 670?678.
  17. Tang E; Cheng G; Pang X; Ma X; Xing F. Synthesis of nano-ZnO/poly(methyl methacrylate) composite microsphere through emulsion polymerization and its UV-shielding property. Colloid Polym Sci. 2006, 248, 422?428.
  18. Son DI; Park DH; Choi WK; Cho SH; Kim WT; Kim TW. Carrier transport in flexible organic bistable devices of ZnO nanoparticles embedded in an insulating poly(methyl methacrylate) polymer layer. Nanotechnology. 2009, 20, 195-203.
  19. Agrawal M; Gupta I; Zafeiropoulos NE; Oertel U; Ha?ler R; Stamm M. Nano-level mixing of ZnO into poly (methyl methacrylate). Macromol. Chem. Phys. 2010, 211, 1925?1932.
  20. Anzlovar A; Kogej K; Crnjak OZ; Zigon M. Polyol mediated nano size zinc oxide and nanocomposites with poly (methyl methacrylate). eXPRESS Polymer Letters. 2011, 5, 604?619.
  21. Matsuyama K; Mishima K; Kato T; Ohara K. Preparation of hollow ZnO microspheres using poly(methyl methacrylate) as a template with supercritical CO2-ethanol solution. Ind. Eng. Chem. Res. 2010, 49, 8510?8517.
  22. Shen W; Xiong H; Xu Y; Cai S; Lu H; Yang P. ZnO-poly(methyl methacrylate) nano beads for enriching and desalting low-abundant proteins followed by directly MALDI-TOF MS analysis. Anal. Chem. 2008; 80, 6758?6763.
  23. Demir MM; Memesa M; Castignolles P; Wegner G. PMMA/Zinc oxide nanocomposites prepared by ın-situ bulk polymerizationa. Macromol. Rapid Commun. 2006; 27, 763?770.
  24. Hong RY; Qian JZ; Cao JX. Synthesis and characterization of PMMA grafted ZnO nanoparticles. Powder Technology. 2006, 163, 160?168.
  25. Matei A; Cernica I; Cadar O; Roman C; Schiopu V. Synthesis and characterization of ZnO ? polymer nanocomposites. Int JMaterForm. 2008, 1, 767?770.
  26. Sato M; Kawata A; Morito S; Sato Y; Yamaguchi I. Preparation and properties of polymer/zinc oxide nanocomposites using functionalized zinc oxide quantum dots. European Polymer Journal 2008, 44, 3430?3438.
  27. Zhao H; Li RKY. A study on the photo-degradation of zinc oxide (ZnO) filled polypropylene nanocomposites. Polymer. 2006, 47, 3207?3217.
  28. Tang E; Liu H; Sun L; Zheng E; Cheng G. Fabrication of zinc oxide/poly(styrene) grafted nanocomposite latex and its dispersion. European Polymer Journal. 2007, 43, 4210?4218.
  29. Xiong HM; Zhao X; Chen JS. New polymer-inorganic nanocomposites: PEO-ZnO and PEO-ZnO-LiClO4 J. Phys. Chem. 2001, 105, 10169-10174.
  30. Loh KJ; Chang D. Zinc oxide nanoparticle-polymeric thin films for dynamic strain sensing. J Mater Sci. 2011, 46, 228?237.
  31. Liufu SC; Xiao HN; Li YP. Thermal analysis and degradation mechanism of polyacrylate/ZnO nanocomposites. Polymer Degradation and Stability. 2005, 87, 103-110.
  32. Moghaddam AB; Nazari T; Badraghi J; Kazemzad M. Synthesis of ZnO nanoparticles and electrodeposition of polypyrrole/ZnO nanocomposite film. Int. J. Electrochem. Sci. 2009, 4, 247-257
  33. Khan AA; Khalid M. Synthesis of nano-sized ZnO and polyaniline-zinc oxide composite: characterization, stability in terms of DC electrical conductivity retention and application in ammonia vapor detection. Journal of Applied Polymer Science. 2010, 117, 1601?1607.
  34. Tang E; Cheng G; Pang X; Ma X; Xing F, Synthesis of nano-ZnO/poly(methyl methacrylate) composite microsphere through emulsion polymerization and its UV-shielding property. Colloid and Polymer Science, 2006, 284(4), 422-428.

[Ahmet Gultek*, Selda Sezer, Imren Ozcan, Suleyman Koytepe and Turgay Seckin. (2017); SPECIFIC HEAT CAPACITY OF FLOWERLIKE ZnO-PMMA COMPOSITES INVESTIGATED BY DSC. Int. J. of Adv. Res. 5 (Apr). 97-111] (ISSN 2320-5407). www.journalijar.com

Ahmet Gültek
Chemistry Department, Inonu University, 44280, Malatya, TURKEY

DOI:

Article DOI: 10.21474/IJAR01/3785      
DOI URL: http://dx.doi.org/10.21474/IJAR01/3785

Download Full Paper

Download PDF No. of Downloads: 68 | No. of Views: 181