SYNTHESIS AND CHARACTERIZATION OF (1E, 2E) - 1, 2 - DIPHENYLETHANE -1, 2 – DIENEHYDRAZONE OXIME LIGAND AND ITS Fe(II) AND Pd(II) METAL COMPLEXES.
- Schoolof Basic Sciences, Jaipur National University, Jaipur-302017, India.
- Department of Chemistry, K.M.Agrawal College, Kalyan-421301, India.
- Department of Chemistry, Institute of Science 15, Madam Cama Road, Mumbai- 400032, India.
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Reaction between hydrazine hydrate 80% aqueous solution and an alcoholic solution of ?-benzilmonoxime yields ?-benzilmonoximehydrazone (IUPAC Name: (1E, 2E) - 1, 2 - diphenylethane -1, 2 –diene hydrazine oxime). The present work report the synthesis and characterization of ?-benzilmonoximehydrazone along with its metal complexes with Fe(II) and Pd(II). The compounds synthesized have been characterized on the basis of various physico-chemical techniques. Electrical conductance studies on the metal complexes reveal their non-electrolytic nature. Spectral measurements and magnetic moment suggest an octahedral geometry for Fe(II) Complex, and square planar geometry for Pd(II) complex. Reaction between hydrazine hydrate 80% aqueous solution and an alcoholic solution of ?-benzilmonoxime yields ?-benzilmonoximehydrazone (IUPAC Name: (1E, 2E) - 1, 2 - diphenylethane -1, 2 –diene hydrazine oxime). The present work report the synthesis and characterization of ?-benzilmonoximehydrazone along with its metal complexes with Fe(II) and Pd(II). The compounds synthesized have been characterized on the basis of various physico-chemical techniques. Electrical conductance studies on the metal complexes reveal their non-electrolytic nature. Spectral measurements and magnetic moment suggest an octahedral geometry for Fe(II) Complex, and square planar geometry for Pd(II) complex.
Raj R. Badekar, R. S. Lokhande, S. W. Kulkarni and R. M. Patil. (2016); SYNTHESIS AND CHARACTERIZATION OF (1E, 2E) - 1, 2 - DIPHENYLETHANE -1, 2 – DIENEHYDRAZONE OXIME LIGAND AND ITS Fe(II) AND Pd(II) METAL COMPLEXES., Int. J. of Adv. Res. 4 (Aug), ISSN 2320-5407. DOI URL: https://dx.doi.org/10.21474/IJAR01/1276
