24Feb 2017

Synthesis, characterization and oxidase biomimetic catalytic activity of copper(II) complexes with pyridine based ligand containing N3S2 donors.

  • Chemistry Department, Faculty of Science, Kafr El-Sheikh University, Kafr El-Sheikh Egypt.
  • Chemistry Department, Faculty of Science, Aswan University, Aswan, Egypt.
  • Chemistry Department, University College in Al-Jamoum, Umm Al-Qura University, 21955, Makkah, Saudi Arabia.
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A new series of hexa-, and five- coordinated copper(II) complexes, having the molecular formulae of [CuLX]X H2O, 1, 2, 3 (X = Cl?, Br?, NO3?) and [CuL]X2 nH2O, 4, 5 (X= AcO? and ClO4?) respectively and L is pentadentate pyridine based ligand have been synthesized. Structural characterization of these newly synthesized compounds was achieved by several physicochemical methods including elemental and thermal analysis (TGA and DTG), electrical molar conductance, magnetic moment measurements and spectral investigations such as IR, UV-Vis and ESR. The spectral and magnetic measurements in addition to the electrolytic conductance results demonstrated the octahedral and square-pyramidal stereochemistries for the hexa, and five coordinated copper(II) chelates respectively. Catechol oxidase and phenoxazinone synthase biomimetic catalytic activity of the inspected copper(II) chelates was studied and the results obtained indicated that, the catalytic reactivity is markedly depends on the structural properties of these newly synthesized copper(II) complexes.

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[Abd El Motaleb M. Ramadan, Asmaa A. Ibrahim, Magda A. Barsy, Asmaa A. Mostafa and Sami A. Al-Harbi. (2017); Synthesis, characterization and oxidase biomimetic catalytic activity of copper(II) complexes with pyridine based ligand containing N3S2 donors. Int. J. of Adv. Res. 5 (Feb). 1197-1210] (ISSN 2320-5407). www.journalijar.com

Abd El Motaleb M. Ramadan1
Chemistry Department, Faculty of Science, Kafr El-Sheikh University, Kafr El-Sheikh Egypt

DOI:

Article DOI: 10.21474/IJAR01/3272      
DOI URL: https://dx.doi.org/10.21474/IJAR01/3272

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