INFLUENCE OF AMINO ACID DOPANTS ON THE GROWTH AND PROPERTIES OF POTASSIUM HYDROGEN PHTHALATE SINGLE CRYSTALS FOR NONLINEAR OPTICAL APPLICATIONS
- PG and Research Department of Physics, Jamal Mohamed College (Autonomous), Affiliated to Bharathidasan University, Trichy-20, Tamilnadu, India.
- PG and Research Department of Physics, Government Arts College, Affiliated to Bharathidasan University, Trichy-22, Tamilnadu, India.
- Abstract
- Keywords
- References
- Cite This Article as
- Corresponding Author
Undoped and the impact of amino acid dopants such as L-Glutamic acid (LGA), L-Asparagine (LAS) and L-Serine (LS) on the growth process and properties of potassium hydrogen phthalate (KHP) single crystal by slow evaporation solution growth technique have been examined. The unit cell parameters of the grown crystals have been affirmed by means of single crystal X-ray diffraction analysis. The crystallinity of the title materials was examined by powder X-ray diffraction. The FT-IR spectral studies identify the presence of expected functional groups of the grown crystals. The optical transmission of the grown crystals has been recorded using UV-Vis spectral analysis. The thermal stability of the grown crystals has been analyzed by TG-DTA studies. Microhardness mechanical studies show that hardness number increases with the load for the grown crystals by Vickers microhardness method. The nonlinear optical (NLO) properties were analyzed utilizing Kurtz and Perry powder technique.
- D. Dodge (1915). The standardization of alkalimetric solutions, J.Ind.Eng.Chem, 7, 29-30.
- Le Moigne, F. Kajzar, and A. Thierry (1991). Single orientation in Poly (diacetylene) films for nonlinear optics Molecular Epitaxy of 1,6-Bis (9-carbazolyl)-2,4-hexadiyne on organic crystals, Macromol, 24, 2622-2628.
- Shahabuddin Khan, T.S. Narasihamurty (1982). Elasto-optic studies on potassium acid phthalate single crystal, J. Mater. Sci. Lett, 1, 268-270.
- Miniewicz, S. Bartkiewicz (1993). On the Electro-optic properties of single crystals of sodium, potassium and Rubidium acid phthalates, Adv. Mater. Opt. Electron, 2,157-163.
- Okaya (1965). The crystal structure of potassium acid phthalate, KC6H4COOH.COO Acta Crytallogr, 19, 879-882.
- H.J. Hottenhuis, J.G.E. Gardeniers, L.A.M.J. Jetten, P. Bennema (1988). Potassium hydrogen phthalate: Relation between crystal structure and crystal morphology, J. Cryst. Growth, 92, 171-188.
- Nisoli, V. Pruneri, V. Magni, S. De Silvestri, G. Dellepiane, D. Comoretto, C. Cuniberti, J. Le Moigne (1994). Ultrafast exciton dynamics in highly oriented polydiacetylene films, Appl. Phys. Lett, 65, 590- 592.
- Timpanaro, A. Sassella, A. Borghesi, W. Porzio, P. Fontaine, M. Goldmann (2001). Crystal Structure of Epitaxial Quaterthiophene Thin Films Grown on Potassium Acid Phthalate, Adv. Mater, 13, 127-130.
- J.P. Van Enckevort, L.A.M.J. Jetten (1982). Surface morphology of the {010} faces of potassium hydrogen phthalate crystals, J. Cryst. Growth, 60, 275-285.
- R. Ester, R. Price, P.J. Halfpenny (1997). An atomic force microscopic investigation of surface degradation of potassium hydrogen phthalate (KAP) crystals caused by removal from solution, J. Cryst. Growth, 182, 95-102.
- Uthayarani, R. Sankar, C.K. Shashidharan Nair (2008). Growth, spectral and thermal properties of KAP single crystals in the presence of DL-Alanine and L-Methionine amino acid dopants, Cryst. Res. Technol, 43,733-739.
- Elakkina Kumaran, P. Kanchana, C. Sekar (2012). Effect of amino acid additives on the growth and physical properties of potassium acid phthalate (KAP) crystalsSpectrochim Acta A, 91, 370-374.
- C. Sajikumar, S. Vinu, C. Krishnan (2015). Studies on structural, optical and thermal properties of L-Histidine doped potassium hydrogen phthalate single crystal, Int.J.Eng.Res.Technol, 4, 525-528.
- Amuthambigai, C.K. Mahadevan, X. Sahaya Shajan (2016). Optical studies of potassium acid phthalate single crystals added with amino acids, Optik., 127, 5935-5941.
- Thomas Joseph Prakash, J. Martin Sam Gnanaraj, S. Shek Dhavud, S. Ekadevasena (2015). Effect of amino acid dopants on the spectral, optical, mechanical and thermal properties of potassium acid phthalate crystals for possible optoelectronic and frequency doubling applications, Opt Laser Technol., 72, 108-115.
- Murugakoothan, R. Mohan Kumar, P.M. Ushasree, R. Jayavel, R. Dhanasekaran, P. Ramasamy (1999). Habit modification of potassium acid phthalate (KAP) single crystals by impurities, J. Cryst. Growth., 207, 325-329.
- Orel, D. Hadzi, F. Cabassi (1975). Infrared and Raman spectra of potassium hydrogen Phthalate, Spectrochim. Acta. A, 31, 169 – 182.
- E. Newkirk, Renette Laware (1962). Thermogravimetric analysis of potassium hydrogen Phthalate, Talanta, 9, 169-173.
- Belcher, L. Erdey, F. Paulik, G. Liptay (1960). A derivatographic study of potassium hydrogen phthalate, Talanta, 5, 53-57.
- G. Kunjomana, K.A. Chandrasekharan (2005). Microhardness studies of GaTe Whiskers, Cryst. Res.Technol, 40, 782-785.
- Uthayarani, R. Sankar, C.K. Shashidharan Nair (2008). Growth, spectral and thermal properties of KAP single crystals in the presence of DL-Alanine and L-Methionine amino acid dopants, Cryst. Res. Technol, 43, 733-739.
- K. Kurtz and T.T. Perry (1968). A Powder Technique for the Evaluation of Nonlinear Optical Materials, J. Appld. Phys, 39, 3798-3812.
[S. Shek Dhavud and J. Thomas Joseph Prakash. (2017); INFLUENCE OF AMINO ACID DOPANTS ON THE GROWTH AND PROPERTIES OF POTASSIUM HYDROGEN PHTHALATE SINGLE CRYSTALS FOR NONLINEAR OPTICAL APPLICATIONS Int. J. of Adv. Res. 5 (Feb). 886-897] (ISSN 2320-5407). www.journalijar.com
PG and Research Department of Physics, Government Arts College (Affiliated to Bharathidasan University), Trichy-22, Tamilnadu, India.