SOME NEW OXALATO AND SULFATO SNR3 (R=Me, Ph) AND SnR2Cl (R=Ph, Bu) RESIDUES CONTAINING DERIVATIVES AND COMPLEXES: SYNTHESIS, INFRARED, NMR AND MOSSBAUER STUDIES.
- Universit? Cheikh Anta Diop, Facult? des Sciences et Techniques, D?partement de Chimie, Laboratoire de Chimie Min?rale et Analytique, Dakar, S?n?gal.
- Universit? Cheikh Anta Diop, Facult? des Sciences et Technologies de l??ducation et de la Formation (FASTEF), D?partement de Physique-Chimie.
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Ten new oxalato and sulfato complexes and derivatives containing SnR3 or SnR2 (R=Ph, Me, Bu) have been synthetized and studied by infrared, NMR and Mossbauer spectroscopies. The suggested structures are discretes, infinite or oligomers. The environments around the tin centre are trigonal bipyramidal or octahedral, the oxalate and sulfate anions behave as monochelating and bidentate ligands. When cations are involved, supramolecular architectures are obtained.
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[Waly Diallo, Assane Toure, Cheikh A. Khadir Diop and Mamadou Sidibe. (2018); SOME NEW OXALATO AND SULFATO SNR3 (R=Me, Ph) AND SnR2Cl (R=Ph, Bu) RESIDUES CONTAINING DERIVATIVES AND COMPLEXES: SYNTHESIS, INFRARED, NMR AND MOSSBAUER STUDIES. Int. J. of Adv. Res. 6 (Feb). 861-870] (ISSN 2320-5407). www.journalijar.com






