ONE-STEP SYNTHETIC OFP-TERT-BUTYLCALIX[4]ARENE DERIVATIVE VIA DIRECT BENZOYLATION: MECHANISM REACTION STUDIES

  • Department of Chemistry, Faculty of Mathematics- and Natural Sciences, Jember UniversityJl. Kalimantan 37, Jember Indonesia 681752.
  • Departement of Chemistry, Faculty of Mathematics and Natural Sciences, Gadjah Mada University.
Crossref Cited-by Linking logo

  • Abstract
  • Keywords
  • Cite This Article as
  • Corresponding Author

The aim of research the synthesis of 5,11,17,23-tetra(t-butyl)-25-monohydroxy-26,27,28-tribenzoyloxycalix[4]arene (TBMTCA) material were by one-step synthesized by benzoylation reaction of 5,11,17,23-tetra(t-butyl)-25,26,27,28-tetrahydroxycalix[4]arene (TBCA) and benzoyl chloride is (1: 3,7) mol and the refluxing 3 hours at room temperature and predicted mechanism reaction models. The product reaction of synthesis was carried out by means of FTIR and 1H-NMR spectroscopy. The results material of5,11,17,23-tetra(t-butyl)-25-monohydroxy-26,27,28-tribenzoyloxycalix[4]arene (TBMTCA)synthesized was light yellow crystalline having melting point 306-3090C in 90,2 % yields.

[Busroni, Sri Juari Santosa and Chairil Anwar (2022); ONE-STEP SYNTHETIC OFP-TERT-BUTYLCALIX[4]ARENE DERIVATIVE VIA DIRECT BENZOYLATION: MECHANISM REACTION STUDIES Int. J. of Adv. Res. 10 (Nov). 207-210] (ISSN 2320-5407). www.journalijar.com

Busroni
Jember University
Indonesia

DOI:

Article DOI: 10.21474/IJAR01/15659      
DOI URL: https://dx.doi.org/10.21474/IJAR01/15659

Download Full Paper

Download PDF No. of Downloads: 8 | No. of Views: 59