Synthesis, Characterization, Analytical ,Thermal Analysis Studies of Schiff Base And Their Metal Ion Complexes
- Chemistry Department ,College of Science, Basra University.
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The research includes preparation of Schiff bases of salicylidene[ 4-Bromo aniline & 3—Bromo aniline ] derived from condensation reaction of substituted aniline with salicylaldehyed . . The identity of this ligand and its metal (Ni+2 &Co+2) ions complexes have been characterized by elemental analysis ,UV –Vis. ,FTIR&thermal analysis .The IR &UV-Vis.spectral data suggest that ,the ligand behaves as didentate ligand towards the central metal ion with nitrogen donor atoms .From UV –Vis. Data the stoichemsitry of complexes (1:2)(M:L) was found .The thermal behaviour (TGA)of complexes was studied and thermodynamic parameters were determined by Horowitz –Metzger.
[Hanaa H. Haddad (2015); Synthesis, Characterization, Analytical ,Thermal Analysis Studies of Schiff Base And Their Metal Ion Complexes Int. J. of Adv. Res. 3 (Jun). 196-200] (ISSN 2320-5407). www.journalijar.com