PRELIMINARY STUDY OF GLYCEROL ESTER USAGE AS PRIMARY AND SECONDARY EMULSIFIER ON OIL BASED MUD FORMULATION.
- Post Graduate Program of Agroindustrial Technology, Bogor Agricultural University, Bogor 16680, West Java, Indonesia.
- Surfactant and Bioenergy Research Center, LPPM IPB, Pajajaran Street, IPB Baranangsiang, Bogor 16153, Indonesia.
- Program Study of Oil Engineering, Bandung Instutute of Technology, Bandung, Indonesia.
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Glycerol ester is a glycerol derivative product as more value-added byproduct of biodiesel industry. Glycerol ester is obtained by esterification reaction between glycerol and palm oil oleic acid with the addition of methyl ester sulfonic acid (MESA) as catalyst. Glycerol ester is palm oil derivative which is not toxic and renewable. One potential use of glycerol esters is as one components of oil-based formulation for petroleum drilling needs as emulsifier substitute. Emulsifier in drilling mud formulations serves to produce a stable emulsion between oil and water. Emulsifier in drilling fluid formulations commonly used come from petroleum derivatives that non-renewable and expensive. To be used as emulsifier substitute in drilling fluid formulations, glycerol esters must provide test results that are not significantly different from emulsifier derived from petroleum. The purpose of this study is to obtain glycerol ester concentration that will be added in the formulation as emulsifier substitute material in drilling fluids formulation for oil drilling. The concentration of glycerol ester added is as much as 5 lb/bbl, 10 lb/bbl, 15 lb/bbl and 20lb/bbl. Tests on the formulation is include density, viscosity, gel strength, plastic viscosity, yield point, electrical stability, oil water ratio, excess lime, the percentage of water and oil, and HPHT filtrate at temperatures of 350 ?F and pressure of 650 psi. The analysis showed that the best test for blanko is glycerol ester with a concentration of 5 lb/bbl. The results are expected to be used as an alternative to substitute the emulsifier derived from petroleum with emulsifier from palm oil.
- Adams N. J., Charrier, (1985) Drilling Engineering, Complete Well Planning Approach. Tulsa : Penn Well Publishing Company.
- Amoco Production Company (1994) Drilling Fluids Manual. Texas: Amoco Production Company.
- [API] American Petroleum Institute. 2003. Specification for drilling-fluid materials ? Specification 13A. Washington DC: American Petroleum Institute.
- [API] American Petroleum Institute. 2004. API Recommended Practice Standard Procedure for Field Testing Oil-Based Drilling Fluids 13B-1 3rd Edition: Exploration and Production Departement. Washington DC: American Petroleum Institute.?
- [API] American Petroleum Institute. 2005. API Recommended Practice For Field Testing of Oil Based Drilling Fluids13b-2 Fourth Edition, March (2005) ?Washington DC: American Petroleum Institute.
- Nedham M., D., (1995) Drilling Engineering Workbook: A distributed learning course. United State of America: Baker Hughes INTEQ.
- Emmanuella W.Y.P, Panca W, Risnawati (2010) Penelitian desain lumpur untuk mengatasi terjadinya pengendapan oleh material lumpur maupun formasi akibat pengaruh temperatur tinggi dan kontaminan fluida formasi. Lembaran publikasi LEMIGAS. Vol.44 No 2 Agustus 2010:171-184.
- Hou P.W., Yun-Peng Z., David G. (2003) Emulsifierforoil-based drilling fluid. US Patent No. 2003/0130135 A1
- Kendel E.,M. (2012) Synthesis and performance of glycerol ester-based nonionic Der Chemica Sinica. 2 (3): 88-98
- Moore P.,L. (1974) Drilling Practice Manual. Tulsa : Penn Well Publishing Company.
- Muller H., Maker D., Herzog N. (2012) Oligoglycerol Fatty Acid Ester Thickeners for Oil-Based Drilling Fluids. US Patent No. 8153562 B2.
- Noureddini H., Zhu D. (1997) Kinetics of transesterification of Soybean oil. JAOCS 74 (11): 1457-1463.
- Othmer K. 1990. Encyclopedia of chemical technology, 4th edition. Volume 1: A to Alkaloids. John Wiley & Sons Inc.
- Pouilloux Y.S., Abro C., Vanhove J., Barrault. (1998) Reaction of glycerol with fatty acids in the presence of ion-exchange resins Preparation of monoglycerides. Journal of Molecular Catalysis A: Chemical 149 (1-2): 243?254
- Perrin D.D., Armarego W.L.F. (1988) Purification of Laboratory Chemicals. Oxford: Pergamon Press
- Rafi M. (2015) Purity enhancement of 80% palm oil glycerol using vacuum distillation scale 25 litre [Thesis]. Indonesia: Bogor Agricultural University.
- Rubiandini Rudi, Widrajat A., Yakob W., Galih, C, Deni, E, Yosep D. (2006)? Base Oil Baru Buatan Dalam Negeri Yang Tidak Bersifat Toksik Untuk Lumpur Berbahan Dasar Minyak (OBM).Jurnal Teknologi Minyak dan Gas Bumi. Prosiding, Simposium Nasional Ikatan Ahli Teknik Perminyakan Indonesia (IATMI), Bandung, 16-18 November 2005. Institut Teknologi Bandung (ITB). Bandung.
- Ryen C. (2011) Composition and Properties of Drilling and Completion Fluids. Amsterdam: Elsevier.Inc
- Soares L.P., Elizabeth R.L., Rodrigues Jr. J de A., Batista L. N., Nascimento R.S.V. ?(2011) New Applications for Soybean Biodiesel Glycerol Prof. Tzi-Bun Ng (Ed.). In Tech: Croatia
- Westfechtel A., Diana M., Heinz M. (2012) Oligoglycerol fatty acid ester additives for water-based drilling fluids. US Patent No. 8148305.
[Vonny Indah Sari, Erliza Hambali, Ani Suryani, Pudji Permadi and Bonar Tua Halomoan Marbun. (2017); PRELIMINARY STUDY OF GLYCEROL ESTER USAGE AS PRIMARY AND SECONDARY EMULSIFIER ON OIL BASED MUD FORMULATION. Int. J. of Adv. Res. 5 (May). 1264-1273] (ISSN 2320-5407). www.journalijar.com
Bogor Agricultural University