Vol. 5 (05) pp. 1096-1108 DOI: 10.21474/IJAR01/4220

TRICLOSAN MODIFIED STABLE MELAMINE RESIN AS LONG-LASTING ANTIMICROBIAL AGENT.

and
  • Department of Chemistry, GC University, Katchery Road, Lahore 54000, Pakistan.
29 Downloads 154 Views
Crossref

Download Full Paper (PDF)

Abstract

Antimicrobial property of triclosan is diminished due to leaching out from the substrate during washing. A non-leaching permanent antimicrobial finish for cotton fabrics in textile was prepared by condensation reaction of hexa-methylolated melamine with triclosan and further etherification with ethylene glycol to stabilize the resin. Resin was characterized for molecular structure by FTIR and molecular weight by viscometric method. Bacterial strains were used to test inhibition of triclosan modified melamine formaldehyde resin in comparison with conventional leachable triclosan. Triclosan modified melamine formaldehyde resin showed dynamic inhibitory action against bacteria such as Escherichia coli, Staphylococcus aureous. A rapid decrease was observed in bacterial count within 48 hours. It was also observed that resin treatment had significant effect on fabric strength, crease recovery angle, stiffness and whiteness index due to resin crosslinking reaction. Resin coating on fabric showed very good wash fastness with long lasting antimicrobial properties in comparison with triclosan treated fabric. All these properties were achieved due to crosslinking behavior of resin with cellulosic fabric.

Keywords

Article Analytics

References

  1. Gao Y,CranstonR, (2008): Res. J,Recent advances in antimicrobial treatments of textiles, 60-72 78(1).
  2. Purwar RM, Joshi, (2004): Rev,Recent Developments in Antimicrobial Finishing of Textiles--A Review, 4(3).
  3. Simoncic BB, Tomsic, (2010): Res. J,Structures of novel antimicrobial agents for textiles-A review, 1721-1737 80
  4. Donaruma LG, (1975): Polym. Sci,Synthetic biologically active polymers, 1-25 4
  5. Ackart WR, Camp W, Wheelwright J, Byck, (1975): Biomed. Mater. Res,Antimicrobial polymers, 55-68 9(1).
  6. Chandra, MR, Neelamma B, Mouli BC, Rao DS, (2016): Int J Pharm Pharm,Synthesis, antimicrobial screening studies of some terpolymer resins derived from 2, 4-dihydroxyphenyl alkyl ketone, melamine and furfural,
  7. Sandra M, MD, Jo?o F, Paulo C, In?sP,Dmitry E, (2016): Materials,High Pressure Laminates with Antimicrobial Properties, 100 9(2).
  8. Palza H, (2015): Int J Mol Sci,Antimicrobial Polymers with Metal Nanoparticles, 2099 16(1).
  9. Tashiro T, (2001): Mater. Eng,Antibacterial and Bacterium Adsorbing Macromolecules, 63-87 286(2).
  10. Dante RC, DA Santamaria, JM Gil, (2009): Appl. Polym. Sci,Crosslinking and thermal stability of thermosets based on novolak and melamine, 4059-4065 114(6).
  11. Naz MY, Sulaiman SA, Ariwahjoedi BS,Ku K, (2014): World. J,Characterization of modified tapioca starch solutions and their sprays for high temperature coating applications, 2014
  12. Santhanalakshmi J, (1987): Acta,Studies on the thermal decomposition of thermosetting aniline-formaldehyde resins, 321-327 119(2).
  13. Stark W, (2010): Polym Test,Investigation of curing behaviour of melamine/phenolic (MP) thermosets, 723-728 29(6).
  14. Christensen G, (1977): Prog Org Coat,Analysis of functional groups in amino resins, 255-276 5(3).
  15. Ricciotti L, Roviello G,Tarallo O, Borbone F, Ferone C,Cioffi R, (2013): Int J Mol Sci,Synthesis and Characterizations of Melamine-Based Epoxy Resins, 18200 14(9).
  16. Kim SH,J Kim, (2006): Thermochim Acta,Thermal stability and viscoelastic properties of MF/PVAc hybrid resins on the adhesion for engineered flooring in under heating system; ONDOL, 134-140 444(2).
  17. Batista MA, J Moraes, RP BJC S, Oliveira P,CSantos AM, (2011): Prog Org Coat,Effect of the polyester chemical structure on the stability of polyester?melamine coatings when exposed to accelerated weathering, 265-273 71(3).
  18. Bauer DR, (1986): Prog Org Coat,Melamine/formaldehyde crosslinkers: characterization, network formation and crosslink degradation, 193-218 14(3).
  19. Ullah SF, AhmadP.S.M.M. Yusoff, (2013): J Appl Polym Sci,Effect of boric acid and melamine on the intumescent fire-retardant coating composition for the fire protection of structural steel substrates, 2983-2993 128(5).
  20. Bal A I, AcarG, G??l?, (2012): J Appl Polym Sci,A novel type nanocomposite coating based on alkyd‐melamine formaldehyde resin containing modified silica: Preparation and film properties, 125(S1).
  21. Zanetti M A, Pizzi M, Beaujean H, Pasch K, RodeP, Dalet, (2002): J Appl Polym Sci,Acetals-induced strength increase of melamine?urea?formaldehyde (MUF) polycondensation adhesives. II. Solubility and colloidal state disruption, 1855-1862 86(8).
  22. A PizziK, L Mittal, (2003): Handbook of Adhesive Technology,"Melamine-formaldehyde resins,? A. Pizzi and K. L. Mittal, Eds., Marcel Dekker, New York, NY, USA, 2nd edition
  23. Nemli GM, Usta, (2004): Build Environ,Influences of some manufacturing factors on the important quality properties of melamine-impregnated papers, 567-570 39(5).
  24. levy CW, (1999): nature,molecular basis of triclosan activity, 383-384 398(6726).
  25. Pract J.C.D.P.C.D.: HSDB (Hazardous Substance Data bank), search: Triclosan. http://toxnet.nlm.nih.gov/cgibin/sis/search,
  26. Assadi K.A.R.A.A, (2016): Global Pure Appl. Sci,Synthesis and characterization of new oxime-formaldhyde polymer and their biological activities, 1-12 4(1).
  27. (1981): American Journal of Public Health,Association News, 362-448 71(4).
  28. Xue Y, H Xiao,Y Zhang, (2015): Int J Mol Sci,Antimicrobial Polymeric Materials with Quaternary Ammonium and Phosphonium Salts, 3626 16(2).
  29. Tom?ič B, Simončič B, Orel B, ?erjav M, Schroers H, Simončič AS, (2009): Carbohyd Polym,Antimicrobial activity of AgCl embedded in a silica matrix on cotton fabric, 618-626 75(4).
  30. Toda C M,M, Rodriguez LS, Paleari AG, Pero AC, Compagnoni MA, (2015): J Contemp Dent Pract,Antimicrobial activity of a tissue conditioner combined with a biocide polymer, 101-106 16(2).
 

How to Cite This Article

Rashid Saleem and Syed Ahmad Raza Bokhari. (2017); TRICLOSAN MODIFIED STABLE MELAMINE RESIN AS LONG-LASTING ANTIMICROBIAL AGENT., Int. J. of Adv. Res., 5 (05), 1096-1108, ISSN 2320-5407. DOI: https://doi.org/10.21474/IJAR01/4220

Corresponding Author

Rashid Saleem
Researcher
Creative Commons Attribution 4.0 This work is licensed under a Creative Commons Attribution 4.0 International License.