24Jun 2017

GREEN SYNTHESIS, CHARACTERIZATION AND ELECTROCATALYTIC APPLICATION OF CURCUMIN CONJUGATED RUTHENIUM NANOPARTICLES.

  • Department of Analytical Chemistry, School of Chemical Sciences, University of Madras, Guindy Campus, Chennai-600 025, Tamilnadu, India.
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Noble metal nanoparticles are emerging as important materials among the rapidly expanding domains with potential applications in many fields. In this work Ruthenium nanoparticles (RuNP) have been synthesized by a green synthetic pathway using citric acid as the reducing agent and curcumin as the stabilizing agent. The synthesized nanoparticles have been characterised by SEM, XRD and UV-vis spectroscopy. The nanoparticles have been used as an electrocatalyst for the determination of Hydrogen peroxide (H2O2). The RuNP modified electrode response under hydrodynamic conditions has been studied using various voltammetric techniques. The electrode shows a good response towards electrocatalytic reduction of H2O2 with a linear range from 1.66 ?M to 54.70 ?M. The utility of the sensor for real sample analysis has been evaluated by carrying out analysis of different milk samples and the results obtained were found to be satisfactory. The work demonstrates that the new RuNP modified electrode is a promising tool for detection of important analytes.

  1. Anderson AM, Mitchell MS, Mohan RS (2000) Isolation of curcumin from turmeric.J Chem?? Educ?77:359-360
  2. Brar SK, Verma M, Tyagi RD, Surampalli RY (2010) Engineered nanoparticles in wastewater and wastewater sludge ? evidence and impacts, Waste Manage30:504?520
  3. Bystrzejewska-Piotrowska G, Golimowski J, Urban PL (2009) Nanoparticles: their potential??????????????? toxicity, Waste Environ Manage, Waste Manage. 29:2587?2595
  4. Campos-Martin JM, Blanco-Brieva G, Fierro JLG (2006) Hydrogen peroxide synthesis: an outlook beyond the anthraquinone process. AngwChemIntEd45:6962?6984
  5. Cen C, Thiel S, Mannhart J, Levy J (2009) Oxide Nanoelectronics on Demand. Science 323:1026-1030
  6. Conroy S, Jerry HSL, Zhang M (2008) Magnetic nanoparticles in MR imaging and drug Adv Drug Deliv Rev60:1252?1265
  7. Dwivedi AD, Dubey SP, Sillanpaa M, Kwon YN, Lee C, Varma RS (2015) Fate of engineered nanoparticles : implications in the environment. CoordChem Rev287:64-78
  8. Garcia M, Batalla P, Escarpa A (2014) Metallic and polymeric nanowires for electrochemical sensing and biosensing. Trends Anal Chem57:6?22
  9. Hage R, Lienke A (2006) Applications of transition-metal catalysts to textile and wood-pulp bleaching. AngwChemInt Ed45:206?222
  10. Hassan HK, Atta NF, Hamed MM, Galal A, JacobT (2017) Ruthenium nanoparticles-modified reduced graphene prepared by a green method for high-performance supercapacitorapplication in neutral electrolyte.?RSC Advances7:11286-11296
  11. Heilmann A (2003) Polymer Films with Embedded Metal nanoparticles. Berlin: Springer
  12. Heilmann A, Keisow A, Gruner M, Kreibig U (1999) Optical and electrical properties of embedded silver nanoparticles at low temperatures. Thin Solid Films344:175?178
  13. Huang W, Hua Q, Cao T (2014) Influence and removal of capping ligands on catalytic colloidal nanoparticles.?Catalysis letters144:1355-1369
  14. Ito A, Shinkai M, Honda H, Kobayashi T (2005) Medical application of functionalized magnetic nanoparticles. J BiosciBioeng100:1?11
  15. Ju-Nam Y, Lead JR (2008) Manufactured nanoparticles: an overview of their chemistry, interactions and potential environmental implications. Sci Total Environ400:396?????????????? 414
  16. Kumar P, Mathpal MC, Tripathi AK, Prakash J, Agarwal A, Ahmad MM, (2015) Plasmonic resonance of Ag nanoclusters diffused in soda-lime glasses. PhysChemChemPhys17:8596?603
  17. Kurowska E, Brzozka A, Jarosz M, Sulka GD, Jaskuła M (2014) Silver nanowire array sensor for sensitive and rapid detection of H2O2. ElectrochimActa10:4439?4447
  18. Kundu S, Nithiyanantham U (2013) In situ formation of curcumin stabilized shape-selective Ag nanostructures in aqueous solution and their pronounced SERS activity.?RSC Advances3:25278-25290
  19. Kolev TM, Velcheva EA, Stamboliyska BA, Spiteller M (2005) DFT and experimental studies of the structure and vibrational spectra of curcumin.?International Journal of Quantum Chemistry?102:1069-1079
  20. Li X, Wang L, Wu Q, Chen Z, Lin X (2014) Anonenzymatic hydrogen peroxide sensor based on Au?Ag nanotubes and chitosan film. J ElectroanalChem73:519?523
  21. Lopes WA, Jaeger HM (2001) Hierarchical self-assembly of metal nanostructures on d-block copolymer scaffolds. Nature414:735?738
  22. Mathpal MC, Kumar P, Kumar S, Tripathi AK, Singh MK, Prakash J (2015)Opacity and plasmonic properties of Ag embedded glass basedmetamaterials. RSC Adv5:12555-12562
  23. Mody VV, Rodney S, Singh A, ModyHardik R (2010) Introduction to metallic nanoparticles.J Pharm BioalliedSci2:282?289
  24. Manikandan R, Sriman Narayanan S (2016) Differential Pulse Anodic Stripping Voltammetric Determination of Lead (II) Using Poly Xylenol Orange Modified Electrode.?Electroanalysis29:609-615
  25. Perenboom JAAJ, Wyder P, Meier F (1981) Electronic properties of small metallic ?Physics Reports?78:173-292
  26. Romantsova OV, Ulybin VB (2015) Safety issues of high-concentrated hydrogenperoxide production used as rocket propellant. ActaAstron109:231?234
  27. Sardar R, Funston AM, Mulvaney P, Murray RW (2009) Gold nanoparticle, past, present and future. Langmuir25:13840?13851
  28. Schmid G (1995) Chemical synthesis of large metal clusters and their properties.?Nanostructured materials6:15-24
  29. Scholz F, Meyer B (1994)Electrochemical solid state analysis: state of the art.?Chemical Society Reviews23:341-347
  30. Scholz F, Lange B (1992) Abrasive stripping voltammetry-an electrochemical solid state spectroscopy of wide applicability.?TrAC Trends in Analytical Chemistry?11: 359-367
  31. Seddon EA, Seddon KR (1984) Elsevier, Amsterdam New York pp.1373
  32. Thomas CR, George S, Horst AM, Ji Z, Miller RJ, Peralta-Videa JR, Xia T, Pokhrel S, M?dler L, Gardea-Torresdey JL, Holden PA, Keller AA, Lenihan HS, Nel AE, Zink JI (2011) Nanomaterials in the environment : from materials to high through putscreening to organisms ACS Nano5:13?20
  33. Veal EA, Day AM, Morgan BA (2007) Hydrogen peroxide sensing and signalling.MolCell26:1?14
  34. Youdim MBH, and Tenne M (1987) Methods Enzymol.142:617?626.

[A. Angel, R. Manikandan, Jency Feminus. J, S. Sriman Narayanan and P. N. Deepa. (2017); GREEN SYNTHESIS, CHARACTERIZATION AND ELECTROCATALYTIC APPLICATION OF CURCUMIN CONJUGATED RUTHENIUM NANOPARTICLES. Int. J. of Adv. Res. 5 (Jun). 1494-1502] (ISSN 2320-5407). www.journalijar.com

P.N. Deepa
Department of Analytical Chemistry, School of Chemical Sciences, University of Madras, Guindy Campus, Chennai-600 025, Tamilnadu, India

DOI:

Article DOI: 10.21474/IJAR01/4563      
DOI URL: https://dx.doi.org/10.21474/IJAR01/4563

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