Vol. 5 (09) pp. 574-580 DOI: 10.21474/IJAR01/5362

STUDY OF PB(II) AND FE(III) METAL CATIONS ADSORPTION INTO P-TERT-BUTYLCALIX[4]ARENE AS ADSORBENT: KINETIC ADSORPTION.

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  • Departement of Chemistry, Faculty of Matematics and Natural Sciences, University of Jember, Indonesia.
  • Departement of Chemistry, Faculty of Matematics and Natural Sciences, Gadjah Mada University, Yogyakarta.
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Abstract

This research explain the study about compound of 5,11,17,23-tetra(t-Butyl)-25,26,27,28-tetrahidroxycalix[4]arene (TBCA) that will be used as adsorption material for heavy metal cations. Adsorption using immersion method with variations such as the value of acidity (pH), time of exposure and initial concentration of metal cations have been conducted. The results of each investigation showed that the optimum pH of adsorption was at pH = 5 for metal cations of Pb(II) and Fe (III). The observation results showed the optimum time exposure of cation adsorption of Pb(II) and Fe(III) was 90 minutes. Study about kinetic adsorption of Pb(II) metal cations of the adsorbent refered the Ho kinetic model, pseudo second order with rate constant of adsorption 143x10-3 g.mol-1.min-1 and Fe(III) refered the Lagergren kinetics model, pseudo first order with the rate constant of 9.21 x 10-3 min-1. The observation of the study showed that the isotherms adsorption for metal cations of Pb(II) and Fe(III) refered the pattern trend of Langmuir isotherm models. The value of the optimum capacity for metal cation adsorption Pb(II) and Fe(III) each was 128.46 mg/g and 156.09 mg/g respectively. Adsorption energy for Pb(II) and Fe(III) was 5.81 k.J/mol and 7.01 kJ / mol, respectively.

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How to Cite This Article

Busroni, Siswanta. D, Santosa. S. J and Jumina. (2017); STUDY OF PB(II) AND FE(III) METAL CATIONS ADSORPTION INTO P-TERT-BUTYLCALIX[4]ARENE AS ADSORBENT: KINETIC ADSORPTION., Int. J. of Adv. Res., 5 (09), 574-580, ISSN 2320-5407. DOI: https://doi.org/10.21474/IJAR01/5362

Corresponding Author

Busroni
University of Jember
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