Vol. 5 (09) pp. 856-860 DOI: 10.21474/IJAR01/5399

VOLTAMMETRIC STRUCTURE-ACTIVITY QUANTIFICATION OF REGIO-ISOMERS OF DIHYDROXYBENZOIC ACID: ELUCIDATION OF STERIC CONSTRAINTS DURING RAPID IODINATION BY AQUEOUS SOLUTIONS DEVOID OF IODIDE IONS.

, , and
  • Post-Graduate Department of Chemistry, NowrosjeeWadia College, Affiliated to the SavitribaiPhule University, Pune- 411001, India.
13 Downloads 113 Views
Crossref

Download Full Paper (PDF)

Abstract

The reactivity of three regio-isomers of dihydroxybenzoic acid in aqueous medium has been assessed on a quantitative scaffold by voltammetry. The rapid iodination kinetics of these isomers by aqueous molecular iodine solutions devoid of iodide ions has been investigated and the data invoked to elucidate the steric compulsions in the dynamics of these reactions.

Keywords

How to Cite This Article

R. P. Yadav, B. B. Bahule, V. T. Borkar and *V. T. Dangat. (2017); VOLTAMMETRIC STRUCTURE-ACTIVITY QUANTIFICATION OF REGIO-ISOMERS OF DIHYDROXYBENZOIC ACID: ELUCIDATION OF STERIC CONSTRAINTS DURING RAPID IODINATION BY AQUEOUS SOLUTIONS DEVOID OF IODIDE IONS., International Journal of Advanced Research (IJAR), 5 (09), 856-860, ISSN 2320-5407. DOI: https://doi.org/10.21474/IJAR01/5399

Corresponding Author

V.T.DANGAT
Post-Graduate Department of Chemistry, Nowrosjee Wadia College,

Article Analytics

References

  1. Borkar V.T., Bonde S.L and Dangat V.T., (2013) International Journal of Chemical Kinetics.,45,11,693-702.
  2. Ross A.B., Kamal-Eldin A and Aman P., (2004).,Nutr Rev.,62(3),81-95.
  3. Koskela A.,Linko-Parvinen A.M.,Hiisivuori P., Samaletdin A., Kamal-Eldin A.,Tikkanen M.J and Adlercreutz H.,(2007)., Clin Chem., 53(7), 1380.
  4. Clibbens and Nierenstein.,(1915)., J.Am.Chem.Soc.,107,1494.
  5. Mahajan S.K., Chaudhari R.Y and Wagh R.S.,(2011).,Journal of Pharmacy Research.,4(7),2285-2287.
  6. Sroka Z and Ciwoski W.,(2003).,Department of Poland.,1,50-144.
  7. Kubo I.,Xiao P and fujita K.,(2001).,Bioorganic Chemistry Letters.,11.347.
  8. Thomsen I and Torssell K.B.,(1991).,Acta.Chem.Scand.,45,539-542.
  9. , Zhengxing He.,JinghuaXue.,Xiaoping Chen andXiaoyi Wei.,(2010).,Journal of Natural Products.,73,5.
  10. Clayden J., Greeves N and Warren S.,(20120., Organic Chemistry., 2nd edition., Oxford University Press., New York.
Creative Commons Attribution 4.0 This work is licensed under a Creative Commons Attribution 4.0 International License.