Vol. 7 (10) pp. 1310-1317 DOI: 10.21474/IJAR01/9960

COMPARATIVE STRUCTURAL STUDIES OF LINI0.8CO0.1MN0.1O2 CATHODE MATERIALS PREPARED BY SOL - GEL VERSUS SOLID - STATE - REACTION METHOD

, , and
  • Department of Physics, Andhra University, Visakhapatnam
  • Department of Engineering Physics, Andhra University College of Engineering (A), Andhra University, Visakhapatnam
40 Downloads 145 Views
Crossref

Download Full Paper (PDF)

Abstract

In the present work, the layered structure oxide LiNi0.8Co0.1Mn0.1O2 (NCM 811) is synthesized by sol-gel auto combustion and solid state reaction methods. Microstructural and optical properties are investigated by XRD, FE-SEM with EDS, FT-IR and bonding nature studies. Characterization of the crystalline powders, phase identification, particle size examination, and morphological studies are done using XRD and FE-SEM. From FT-IR and UV-NIR studies, vibrational bands are identified in the range of 400-2000 cm-1 representing the MO2 (M = Ni, Co & Mn) layers

Keywords

Article Analytics

References

  1. Eom,?M.G.?Kim,?J.?ChoStorage characteristics of LiNi0.8Co0.1+xMn0.1−xO2?(x=0, 0.03, and 0.06) cathode materials for Lithium batteries, J. Electrochem. Soc.,?155?(2008), p.?A239
  2. -Y.?Liao,?A.?ManthiramSurface-modified concentration-gradient Ni-rich layered oxide cathodes for high-energy lithium-ion batteries, J. Power Sources,?282?(2015), pp.?429-436
  3. Su,?Y.?Yang,?L.?Chen,?Y.?Lu,?L.?Bao,?G.?Chen,?Z.?Yang,?Q.?Zhang,?J.?Wang,?R.?Chen,?S.?Chen,?F.?WuImproving the cycling stability of Ni-rich cathode materials by fabricating surface rock salt phase, Electrochim. Acta,?292?(2018), pp.?217-226
  4. Fu,?D.?Mu,?B.?Wu,?J.?Bi,?H.?Cui,?H.?Yang,?H.?Wu,?F.?WuElectrochemical properties of the LiNi0.6Co0.2Mn0.2O2?cathode material modified by Lithium tungstate under high voltage, ACS Appl. Mater. Interfaces,?10?(2018), pp.?19704-19711
  5. Zhang,?H.?Wang,?L.?Wang,?Y.?CaoHigh electrochemical performance of hollow corn-like LiNi0.8Co0.1M?0.1O2?cathode material for lithium-ion batteries, Appl. Surf. Sci.,?450?(2018), pp.?461-467
  6. Chen,?T.?He,?Y.?Su,?Y.?Lu,?L.?Bao,?L.?Chen,?Q.?Zhang,?J.?Wang,?R.?Chen,?F.?WuNi-rich LiNi0.8Co0.1Mn0.1O2?oxide coated by dual-conductive layers as high performance cathode material for Lithium-ion batteries, ACS Appl. Mater. Interfaces,?9?(2017), pp.?29732-29743
  7. Xiong,?Z.?Wang,?P.?Yue,?H.?Guo,?F.?Wu,?J.?Wang,?X.?LiWashing effects on electrochemical performance and storage characteristics of LiNi0.8Co0.1Mn0.1O2?as cathode material for lithium-ion batteries, J. Power Sources,?222?(2013), pp.?318-325
  8. Li,?X.?Li,?Z.?Wang,?H.?GuoA?short process for the efficient utilization of transition-metal chlorides in lithium-ion batteries: a case of Ni0.8Co0.1Mn0.1O1.1?and LiNi0.8Co0.1Mn0.1O2, J.?Power Sources,?342?(2017), pp.?495-503
  9. Su,?G.?Chen,?L.?Chen,?W.?Li,?Q.?Zhang,?Z.?Yang,?Y.?Lu,?L.?Bao,?J.?Tan,?R.?ChenExposing the {010} planes by oriented self-assembly with nanosheets to improve the electrochemical performances of Ni-Rich Li[Ni0.8Co0.1Mn0.1]O2?microspheres, ACS Appl. Mater. Interfaces,?10?(2018), pp.?6307-6414.
  10. Du?R.,?Bi?Y.,?Yang?W.,?Peng?Z.,?Liu?M.,?Liu?Y.,?Wu?B.,?Yang?B.,?Ding?F.,?Wang?D.Improved cyclic stability of LiNi8Co0.1Mn0.1O2via Ti substitution with a cut-off potential of 4.5V, Ceram Int,?41?(2015), pp.?7133-7139
  11. Cho,?T.-J.?Kim,?J.?Kim,?M.?Noh,?B.?ParkSynthesis, thermal, and electrochemical properties of AlPO4-coated LiNi0.8Co0.1Mn0.1 O 2 cathode materials for a Li-Ion Cell, J. Electrochem. Soc.,?151?(2004) A1899-A1904
  12. Huang,?X.?Zhang,?R.?Yu,?S.?Jamil,?S.?Cao,?S.?Fang,?Y.?Wang,?K.?Tang,?G.?Chen,?Z.?Luo,?X.?Yang,?X.?WangPreparation and performance of the heterostructured material with a Ni-rich layered oxide core and a LiNi0.5Mn1.5O4-like spinel shell, ACS Appl. Mater. Interfaces,?11?(2019), pp.?16556-16566
  13. Kim,?M.G.?Kim,?H.Y.?Jeong,?H.?Nam,?J.?ChoA new coating method for alleviating surface degradation of LiNi0.6Co0.2Mn0.2O2 cathode material: nanoscale surface treatment of primary particles, Nano Lett.,?15?(2015), pp.?2111-2119
  14. Y.?Liao,?A.?ManthiramSurface-modified concentration-gradient Ni-rich layered oxide cathodes for high-energy lithium-ion batteries, J. Power Sources,?282?(2015), pp.?429-436
  15. Chen,?G.-T.?Kim,?Y.?Guang,?D.?Bresser,?T.?Diemant,?Y.?Huang,?M.?Copley,?R.J.?Behm,?S.?Passerini,?Z.?ShenManganese phosphate coated Li[Ni0.6Co0.2Mn0.2]O2 cathode material: towards superior cycling stability at elevated temperature and high voltage, J. Power Sources,?402?(2018), pp.?263-271
  16. Xiong,?Z.?Wang,?H.?Guo,?Q.?Zhang,?X.?LiEnhanced electrochemical properties of lithium-reactive V2O5?coated on the LiNi0.8Co0.1Mn0.1O2?cathode material for lithium ion batteries at 60 ?C, J.?Mater. Chem. A,?1?(2012), pp.?1284-1288.
  17. Cho,?H.?Kim,?B.?ParkComparison of overcharge behavior of AlPO4?-coated LiCoO2?and LiNi0.8Co0.1Mn0.1O2?cathode Materials in Li-Ion Cells, J.?Electrochem. Soc.,?151?(2004).
  18. W.?Lee,?M.S.?Kim,?J.H.?Jeong,?D.H.?Kim,?K.Y.?Chung,?K.C.?Roh,?K.B.?KimLi3PO4surface coating on Ni-rich LiNi0.6Co0.2Mn0.2O2?by a citric acid assisted sol-gel method: improved thermal stability and high-voltage performance, J.?Power Sources,?360?(2017), pp.?206-214.
  19. D.?Steiner,?L.?Mu,?J.?Walsh,?M.M.?Rahman,?B.?Zydlewski,?F.M.?Michel,?H.L.?Xin,?D.?Nordlund,?F.?LinAccelerated evolution of surface chemistry determined by temperature and cycling history in nickel-rich layered cathode materials, ACS Appl. Mater. Interfaces,?10?(2018), pp.?23842-23850
  20. Yan,?J.?Zheng,?J.?Liu,?B.?Wang,?X.?Cheng,?Y.?Zhang,?X.?Sun,?C.?Wang,?J.-G.?ZhangTailoring grain boundary structures and chemistry of Ni-rich layered cathodes for enhanced cycle stability of lithium-ion batteries, Nature Energy,?3?(2018), pp.?600-605.
  21. S.?Zhang,?K.?Jin,?L.Z.?Wang,?Y.?Zhang,?X.F.?Li,?Y.H.?Song High capacity Li1.2Mn0.54Ni0.13Co0.13O2cathode materials synthesized using mesocrystal precursors for lithium-ion batteries, J. Alloys Compd.,?638?(2015), pp.?298-304.
  22. Zhang,?H.?Wang,?L.?Wang,?Y.?CaoHigh electrochemical performance of hollow corn-like LiNi0.8Co0.1Mn0.1O2?cathode material for lithium-ion batteries, Appl. Surf. Sci.,?450?(2018), pp.?461-467
  23. Min?Nie,?Yunfei?Xia,?Zhenbo?Wang,?Fuda?Yu,?Yin?Zhang,?Jin?Wu,?Bing?WuEffects of precursor particle size on the performance of LiNi5Co0.2Mn0.3O2cathode material, Ceram. Int.,?41?(2015), pp.?15185-15192
  24. Ilkyu?Hwang,?Chul Wee?Lee,?Jae Chang?Kim,?Songhun?YoonParticle size effect of Ni-rich cathode materials on lithium ion battery performance Res. Bull.,?47?(2012), pp.?73-78
  25. Minmin?Chen,?Enyue?Zhao,?Dongfeng?Chen,?Meimei?Wu,?Songbai?Han,?Qingzhen?Huang,?Limei?Yang,?Xiaoling?Xiao,?Zhongbo?HuDecreasing Li/Ni disorder and improving the electrochemical performances of Ni-rich LiNi8Co0.1Mn0.1O2by Ca doping, Inorg. Chem.,?56?(2017), pp.?8355-8362
  26. Duc-luong?Vu,?Jae-won?LeeNa-doped layered LiNi8Co0.1Mn0.1O2with improved rate capability and cycling stability, J. Solid State Electrochem.,?22?(2018), pp.?1165-1173
  27. Kang?Wu,?Guofeng?Jia,?Xuehui?Shangguan,?Guowei?Yang,?Zenghu?Zhu,?Zhengjun?Peng,?Qin?Zhuge,?Faqiang?Li,?Xiaoling?CuiImproved high rate performance and cycle stability for LiNi8Co0.2O2by doping of the high valence state ion Nb5+?into Li+?sites, J. Alloy. Comp.,?765?(2018), pp.?700-709
  28. Q.?Pham,?G.?Kim,?H.M.?Jung,?S.-W.?Song, Adv. Funct. Mater.,?28?(2018), p.?1704690
  29. Socrates, Infrared Characteristic Group Frequencies, Table?and Charts, (second ed.),?John Wiley& Sons,?New York?(1994)
  30. Vijayamari,?K.?Sadayandi,?Suresh?Sagadevan,?Preeti?Singh, J. Mater. Sci.: Mater. Electron.,?28?(2017), pp.?2739-2746.
  31. Lehlohonolo F. Koao, Setumo V. Motloung, Tshwafo E. Motaung, Mesfin A. Kebede, Physica B: Condensed Matter, 535 (2018) 323-329.
  32. Bai,?Z.?Liu,?D.D.?Sun, Int. J. Hydrog. Energy,?37?(2012), pp.?13998-14008.

How to Cite This Article

V. Kondala Rao, N. Murali, V. Veeraiah and K. Samatha (2019); COMPARATIVE STRUCTURAL STUDIES OF LINI0.8CO0.1MN0.1O2 CATHODE MATERIALS PREPARED BY SOL - GEL VERSUS SOLID - STATE - REACTION METHOD, Int. J. of Adv. Res., 7 (10), 1310-1317, ISSN 2320-5407. DOI: https://doi.org/10.21474/IJAR01/9960

Corresponding Author

N. MURALI
Department of Engineering Physics, Andhra University College of Engineering (A), Andhra University, Visakhapatnam
Creative Commons Attribution 4.0 This work is licensed under a Creative Commons Attribution 4.0 International License.