REACTIVITY OF DISUBSTITUED AMMONIUM SELENIATE SALTS WITH SnMe3CL. X-RAY STRUCTURE OFCy2NH2SeO4SnMe3
- Laboratoire de Chimie Minerale et Analytique, Departement de Chimie,Faculte des Sciences et Techniques, Universite Cheikh Anta Diop, DAKAR, Senegal.
- Faculte des Sciences et Techniques de lEducation et la Formation, Universite Cheikh Anta Diop, DAKAR, Senegal.
- X-Ray Department, ICMCB-CNRS, Universite de Bordeaux, 87, Avenue du Dr Albert Schweitzer 33608 PESSAC France.
Abstract
The reaction of Cy2NH2HSeO4.H2Oand SnMe3Cl led to the formation of Cy2NH2SeO4SnMe3 (1), which crystallizes in the orthorhombic space group Pbca with Z = 16, a = 11.59430(10) AÌŠ, b = 19.3138(3)AÌŠ, c = 36.8673(6)AÌŠ, and V = 8255.7(2)AÌŠ3. The asymmetric unit consists of two [SeO
4
SnMe
3
]- in which the SnMe3 residue is trans coordinated. The complex-anion are linked via NH----O hydrogen bonds which are involved by Cy2NH2+cation. From a supramolecular point of view, the superposition of [SeO4SnMe3]- along a axis are linked by the NH---O of Cy2NH2+cation along c axis giving a tridimensional structure. The characterization of 1 is accompanied by infrared and NMR characterization of two seleniate complexes containing SnMe3 residue to complete the study of reactivity between dialkylammonium seleniate salt and SnMe3Cl molecule.
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How to Cite This Article
Boucar Diouf, Waly Diallo, Mouhamadou Sembene Boye, Daouda Ndoye, Mamadou Sidibe, Abdoul Khadir Diop and Stanislav Pechev (2023); REACTIVITY OF DISUBSTITUED AMMONIUM SELENIATE SALTS WITH SnMe3CL. X-RAY STRUCTURE OFCy2NH2SeO4SnMe3, Int. J. of Adv. Res., 11 (08), 22-29, ISSN 2320-5407. DOI: https://doi.org/10.21474/IJAR01/17356
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