Vol. 3 (05) pp. 1363-1370

Kinetics and Mechanism of Substitution of Aquo – Ligands from cis-Diaquo-Bis (Ethylenediamine) Cobalt (III) ion by o-Phenylenediamine in Ethanol - Water Mixture

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  • 1. Department of Chemistry, Sphoorthy Engineering College (JNTUH), Nadargul (V), Near Vanasthalipuram, Sagar Road, Saroornagar (M), Hyderabad – 501 510 (Telangana State), INDIA.
  • 2. Department of Chemistry, Osmania University, Hyderabad – 500 007 (Telangana State), INDIA.
  • 3. Department of Chemistry, Dayananda Sagar Academy of Technology and Management, Udayapura, Bengaluru – 560 082 (Karnataka State), INDIA
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Abstract

The anation kinetics and mechanism of cis[Co(en)2(H2O)2]3+ by o-phenylenediamine will be described in which the incoming ligand OPDA behaves as a neutral bidentate (N, N) donor. The anation rate has been studied as a function of substrate complex concentration, ionic strength, pH, o-phenylenediamine, temperature and medium dielectric constant.

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How to Cite This Article

Badhe Srinivas, A. Rajeshwar Rao and M. Radhakrishna Reddy (2015); Kinetics and Mechanism of Substitution of Aquo – Ligands from cis-Diaquo-Bis (Ethylenediamine) Cobalt (III) ion by o-Phenylenediamine in Ethanol - Water Mixture, Int. J. of Adv. Res., 3 (05), 1363-1370, ISSN 2320-5407.

Corresponding Author

Dr. Badhe Srinivas

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