KINETIC AND MECHANISTIC STUDIES OF MICELLER CATALYSED OXIDATION OF ISO-BUTYRIC ACID IN PERCHLORIC ACID MEDIUM BY PERMANGANATE.
- Govt. Holkar Science College, A B Road, Indore-452017
- P.M.B. Gujarati Science College, Indore
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Abstract
A kinetic study of oxidation of iso-butyric acid has been investigated in presence of sodium lauryl sulphate an anionic micelle and the miceller catalysed oxidation of iso butyric acid by permanganate in perchloric acid medium. The reaction is a double stage process, in which first stage is followed by second fast stage process. A first order kinetics is observed with respect to substrate and oxidant. The data will examine in the light of Zucker-Hammett, Bunnett and Bunnett-Olsen criteria of reaction mechanism. Kinetic parameters and activation have been determined. Temperature coefficient were determined by varying temperature. The stiochiometry was observed in terms of mole ration of permanganate ion and perchloric ion . salt and surface area effects have been also analysed.
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Parvati Mory1, Dr. Vijay R. Chourey1, Dr. Dhananjay Dwivedi2 (2016); KINETIC AND MECHANISTIC STUDIES OF MICELLER CATALYSED OXIDATION OF ISO-BUTYRIC ACID IN PERCHLORIC ACID MEDIUM BY PERMANGANATE., Int. J. of Adv. Res., 4 (03), 1188-1200, ISSN 2320-5407.
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