ACETYLATION OPTIMIZATION OF SAGO (METROXYLON SAGU ROTT) STARCH FOR EDIBLE FILM PRODUCTION.

  • Maluku Assessment Institute for Agricultural Technology (Maluku AIAT), Indonesia.
  • Departement of Chemistry, Bogor Agricultural University, Dramaga, Bogor-West Java, Indonesia.
  • Departement of Agroindustrial Technology, Bogor Agricultural University, Dramaga, Bogor-West Java, Indonesia.
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Optimization of sago starch acetylation on tensile strength and contact angle of the edible film was investigated using response surface methodology. The operating conditions were the concentrations of acetic acid anhydride, reaction time and pH. The only concentration of acetic acid anhydride and pH value had a significant effect on tensile strength and contact angle. Both acid concentration and pH value had a negative effect on tensile strength, however, had a positive effect on contact angle. The optimum condition of acetylation for tensile strength and contact angle of edible film sago starch acetate was 44% acetic acid anhydride concentration at pH 8.24 and reaction time of 60 minutes. This combination yields 2.80 MPa tensile strength and contact angle 42.18o of edible film sago starch acetate.

  1. Abner L, Miftahorrahman. 2002. KeragamanIndustriSagu Indonesia. Warta PenelitiandanPengembanganTanamanIndustri. 8(1), 2002.
  2. Adebowale KO, and Lawal OS. 2003. Functional properties and retrogradation behaviour of native and chemically modified starch of mucuna bean (Mucuna pruriens). J Sci Food and Agric, 83, 1541?1546
  3. AOAC, 1995. Official Methods of Analysis of AOAC International, 2v (16 ed.). Arlington, TX: Association of Official Analytical Chemistry.
  4. Bae HJ, Cha DS, Whiteside WS, Park HJ. 2008. Film and pharmaceutical hard capsuleformation properties of mungbean, waterchestnut, and sweet potato starches. Food Chem. 106(1): 96?105.
  5. Baldwin EA. 1994. Edible coatings for fresh fruits and vegetables: past, present, and future. In: Krochta JM, Baldwin EA, Nisperos-Carriedo MO, editors. Edible coatings and films toimprove food quality. Lancaster, Pa.: Technomic Publishing Co., Inc. p 25?64.
  6. Chi H, Xu K, Wu X, Chen Q, Xue D, Song C, Zhang W, Wang P. 2008. Effect of acetylation on the properties of corn starch. Food Chem. 106(2008), 923?928.
  7. Colussi R, Pinto V Z, El Halal SLM, Vanier NL, Villanova FA, Marques E Silva R, Dias ARG. 2014. Structural, morphological, and physicochemical properties of acetylated high-, medium-, and low-amylose rice starches. 103(1), 405?413.
  8. Gonzales Z, Perez E. 2002. Effect of acetylation on some properties of rice starch. Starch. 54: 148-154, 2002packaging and preservation. London, U.K.: Elsevier Applied Science Publishers. p 371?94.
  9. Guilbert S. 1986. Technology and application of edible protective films. In: Mathlouthi M, editor. Food packaging and preservation. London, U.K.: Elsevier Applied Science Publishers. p 371?94.
  10. Huang J, Schols HA, Jin Z, Sulmann E, Voragen AGJ. 2007. Pasting properties and (chemical) fine structure of acetylated yellow pea starch is affected by acetylation reagent type and granule size. CarbohydrPolym. 68: 397?406.
  11. Karim AA, Tie AP, Manan DMA, Zaidul ISM. Starch from the Sago (Metroxylonsagu) Palm Tree ? Properties, Prospects, and Challenges as a New Industrial Source for Food and Other Uses, (1977).
  12. Kester J, Fennema O. 1986. Edible films and coatings: a review. Food Technol. 40:47?59.
  13. Kusnandar F. 2010. Kimia PanganKomponenMakro. Seri 1. Dian Rakyat, Jakarta
  14. Kuo WY, Lai HM. 2007. Changes of property and morphology of cationic corn starches. 69(3), 544?553.
  15. Mali S, Grossmann, MVE, Garcı́a MA, Martino MN, Zaritzky NE. 2005. Mechanical and thermal properties of yam starch films. Food Hydrocolloids, 19: 157?164.
  16. Matti E, Tomas A, Pasi S, Reino L, Soili P, Sari H. 2004. Determination of the degree of substitution of acetylated starch by hydrolysis, 1H NMR and TGA/IR. CarbohydrPolym. 57: 261?267.
  17. Oates CG, Hicks A. 2002. Sago starch production in Asia and the Pacific-problems and prospects. In: Proceedings of the International Symposium on Sago (Sago 2001) held on October 15?17 2001, at the Tsukuba International Congress Center Japan. Universal Academy Press Inc., Tokyo, p. 27?36.
  18. Perez LAB, Acevedo EA, Hernandez LS dan O.P. Lopez. 1999. Isolation and Partial Characterization of Banana Starches. J. Agric. Food Chem. 47 : 854 ? 857
  19. Polnaya FJ, Talahatu J, Haryady, Marseno DW. 2009. Karakterisasitigajenispatisagu(metroxylon) hidroksipropil. Agritech, 29(2), 87?95.
  20. Sandhu KS, Sharma L, Kaur, M. 2015. Effect of granule size on physicochemical, morphological, thermal and pasting properties of native and 2-octenyl-1-ylsuccinylated potato starch prepared by dry heating under different pH conditions. LWT - Food Sci Technol.61(1), 224?230.
  21. SIRIM, 1992. Malaysian Standard MS 470: specification for edible sago starch.
  22. Sodhi NS, Singh N. 2005. Characteristics of acetylated starches prepared using starches separated from different rice cultivars. Food Eng. 70(2005), pp.117?127.
  23. Sun R, Sun XF. 2002. Structural and thermal characterization of acetylated rice, wheat, rye, and barley straws and poplar wood fibre. Ind Crops Prod.16(3): 225?235.
  24. Trappey EF, Khouryieh H, Aramouni F, Herald T. 2015. Effect of sorghum flour composition and particle size on quality properties of gluten-free bread. Food Sci Technol 21(3): 188-202.
  25. Tupa MV, Ram?rez JAA, V?zquez A, Foresti MA. 2015. Organocatalytic acetylation of starch: effect of reaction conditions on DS and characterisation of esterified granules. Food Chem. 170: 295?302.
  26. Winger M, Khouryieh H, Aramouni F, Herald TJ. 2014. Sorghum flour characterization and evaluation in gluten-free flour tortilla. J Food Quality. 37(2): 95-106.
  27. Wurzburg OB. Acetylation. In Methods in Carbohydrate Chemistry; Whisther, RL, Smith, RJ, Wolfrom, M L, Eds.; Academic Press: New York, 1964.; Vol IV, pp 240- 241.
  28. Zhou X, Lin X, White KL, Lin S, Wu H, Cao S, Chen L. 2016. Effect of the degree of substitution on the hydrophobicity of acetylated cellulose for production of liquid marbles. Cellulose, 23(1), 811?821.

Rosniyati Suwarda, Tun Tedja Irawadi, Prayoga Suryadarma And Indah Yuliasih. (2019); ACETYLATION OPTIMIZATION OF SAGO (METROXYLON SAGU ROTT) STARCH FOR EDIBLE FILM PRODUCTION., Int. J. of Adv. Res., 7 (05), 1207-1217, ISSN 2320-5407. DOI URL: https://dx.doi.org/10.21474/IJAR01/9153

Tun Tedja Irawadi
Departement of Chemistry, Bogor Agricultural University, Dramaga, Bogor-West Java, Indonesia.

DOI:

Article DOI: 10.21474/IJAR01/9153      
DOI URL: https://dx.doi.org/10.21474/IJAR01/9153

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